The first image is really good although the eyes look dead. Maybe have her eyes with an up/down value of somewhere between -5 and -8. Poser figures can often look more realistic when their eyes are pointing in a certain direction. The eyewhite could have a brighter specular value as well. I agree that the second looks way overexposed. In addition, the resolution of the head and body are often different. The second image makes the body look more pixelated. The eyes look bloodshot and the lipstick doesn't match with the surrounding lip texture. I hope this was helpful and not too critical. You're doing an excellent job :)