I actually paint in a mask over the pupils, with a very soft edge, then go in and desaturate (I use a mask so I don't accidentally desaurate any other part of the eye). Sometimes that's enough right there. If it still doesn't look right, though, I use the burn tool set on a low opacity and very gently darken the pupils. Do it too much and it looks totally weird, so you want to go slowly with it. bonni

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