Quote - Kirk was the first Captain of Enterprise

Or, if you want to pick nits (galactic space-nits, no doubt) the first captain of the Enterprise was, chronologically, Jonathon Archer. Yeah, yeah, yeah, different Enterprise.

Of course, in 1707 there was Captain W. Davenport of the 6th rate vessel Enterprise of the British Navy, which pre-dates 'em all.

(Okay, I guess now I'm off-off topic... )

In any event, it definitely wasn't J.T. Kirk, no matter how you look at it.

Captain Jack