It looks like you have a couple versions of Python installed on your machine with the default version being the the 2.5 Version you have installed on your C: drive.  Normally this wouldn't be a problem. but it appears that the 2.5 version of Python you installed on your C: drive is setting some Windows registry values that point to the wrong place.  What I would recommend is to
upgrade (free) to SkinVue6.3 at Cornucopia 3D - there is a fix in SkinVue6.3 that solves this problem by forcing the import of wxPython to use VuePython paths as the first search path versus anything you might have in your registry.