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I was having the same problems with the mat poses applying on the pose screen but I figured out that you have to apply them in the material room and they will work.

~Jadealis

You can apply them in the pose room by dragging them and dropping them on the figure or prop you want to apply them too.

i think you are supposed to be able to apply them by double clicking, but that may be the bit that doesn't work right.

No that's mostly not working. Why are you answering "I think you are supposed", if you don't know it for sure? However they way you describe it is how it should work but it's not working.

Jadealis is right. Nevertheless a lot of users have then another problem if they want to go back from the materials to the pose room. Instead of the pose room they are led to the morph tools or the animation and then P8 crashes). This was already addressed in other threads and is known as a bug to SM who have received obviously many notes regarding this issue.