I'm a Blender user too.  The clothing I made for Antonia are done in Blender.   There are many good on-line tutorials for you to learn.  Once you used to the shortcut key and the user interface, you will find it is not too hard.  I admit it is not easy as Wings.  If you want to use it to make Poser stuff, I would like to suggest that you scale a item, otherwise, your item is too small to use some of the Blender feature due to the precision.   You may want to use 10 Blender Unit = 1 Poser Unit.