If you have used Poser Pro, you at least have an awarenss of 3D. I have always found Poser Pro more complicated in some areas than Vue. I found editing materials in Vue a lot easier than in Poser. Don't try to compare them as you learn Vue, but your ability to utilize them in Poser Pro will help. Believe me, you will end up having an aha moment when Vue falls into place. then, you will keep learning from there.

Years ago, I wrote tutorials for beginners on Vue. I know they have helped people because I have had requests from websites to translate them into Russian and other languages. They are not videos so can be downloaded and followed. http://www.perpetualvisions.com/tocs/toc-articles.htm

Perhaps those can help you. I, also, second using GeekatPlay and their book. It is a fabulous website. The Vue community owes a lot to them.

Hope this has helped.