Poser uses the material order first found in the obj file. You can easily force a different order thou. 

All you have to do is add a usemtl list to the beginning of the obj file that defines the order you want it to appear.

usemtl 2_SkinTorso

usemtl.............

Etc, etc, etc. Each usemtl call has to be on it's own line, and you want to add all of the materials.

If you have Antonia WM, it has a list to do that in it.

I change the order in many of my characters, which gives the added bonus of alerting you when Poser creates a new obj file. Poser will not add the list to the beginning of the file, and it will go back to the default order if Poser saves out a new OBJ.

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