In the instance tab, highlight "actor' when applying a material set.

Or to apply a shader to a single shader domain, highlight actor, switch to shader room, drag shader and drop to the shader somain, example face

.

Daz shaders come in different flavors, some are iray, some are AoA shaders, both of which are potential propblems in carrara. for example iray opacity won't work. some makeups are setup for Daz Studio's LIE layered imaging.

optionally, you could apply your favorite carrara skin shader. Delphinia is a nice one, then manually load the texture maps you're interest in using. for iray shaders, the alpha map would need to manually be selected.

for make up layers, one option is to play with the shader mixer.
another method is to merge the make up layer with skin in a photo editor - (rhis is the method i use)

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