If I use Windows style path syntax (I'm on Windows 10) it still doesn't work

But with the full absolute path starting "C:\Users\..." it works.

Of course that's no use in a freebie as I have no idea where users will put the file.

So the new question now becomes "can Poser 6 handle runtime relative paths from a runPythonScript statement in a Poser file ?"

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The 3Dcheapskate* occasionally posts sensible stuff. Usually by accident.
And it usually uses Poser 11, with units set to inches. Except when it's using Poser 6 or PP2014, or when its units are set to PNU.

*also available in ShareCG, DAZ, and HiveWire3D flavours (the DeviantArt and CGBytes flavour have been discontinued).