In my punks I usually lighten the skin for that "I never go out in the daylight" look. You also could do some postwork on the hair. BTW what hair is that? It looks really cool.

Very nice - I hope you don't mind if i offer a few suggestions. If you have Photoshop, or Paint shop pro, do a little postwork such as: Using the blur tool, blur all of the edges around the outside of your character and hair creases, just to smudge them a bit. Also blur the part where the eyeliner you drew in meets her skin tone under the eye. You may also want to draw in some additional hair and then blur those a little, and either render over a picture background or render over a color background -maybe either Black or White. Keep working on her - you're off to a great start!

heheh she's meeeaaan-looking i could hopelessly try making a transmap for the hair if you want heheh

You've not only achieved a "punk-look" to your character, but additionally a strong Anime look, similar to many of the more detailed Japanese creations, although the eyes would need to be a tad wider. She could easily become a character of her own strip with the hair exactly as it is. Not all Poser creations need to look photorealistically human. Nice job Esme.